Press your lips together to stop the air, then release. No vocal cord vibration.

Americans pronounce potassium as puh-TA-see-uhm (/pəˈtæsiəm/). Stress falls on the second syllable — keep everything else short and quick. You'll hear it in sentences like "A banana is a good source of potassium".
Record yourself saying "potassium" and play it back. The mic stays on your device — nothing's uploaded.
4 syllables, 8 sounds. Tap a syllable to jump to its row, then explore each sound's mouth shape and how it's made.
Touch the tip or front edge of your tongue to the roof of your mouth just behind your teeth. Keep your jaw relaxed. Stop the air, then release with a puff.

Drop the jaw noticeably. Keep the body of the tongue low and forward, and don't let the back of the tongue raise toward the soft palate. Pull the lip corners back slightly, almost a starting smile.

The textbook way isn't wrong — it's just not how anyone actually says it.
In "potassium", the short unstressed vowel before "m" disappears — the schwa is absorbed and the "m" becomes the syllable nucleus on its own. Schwa is absorbed — consonant becomes the syllable nucleus.
Stress falls on the second syllable, not the others. Stretch TA — keep everything else short and quick.
Don't pronounce the first syllable too fully. The unstressed syllable reduces to a schwa — the lazy "uh" sound — in casual speech.